Hardness, X-ray diffraction and transmission as well as infrared refle
ction measurements on virgin and ultraviolet (UV)-irradiated amorphous
films of the GexAs40-xS60 system have been performed. The UV light in
duces film softening for x < 19 and film hardening for x > 19. The str
ucture remains amorphous but the distance characteristic of medium ran
ge order decreases for x < 19 and increases for x > 19. Photo-contract
ion of the films (up to similar to 12%) has been revealed from IR spec
tra and X-ray transmission experiments. A main effect of UV light is t
he release of sulphur. (C) 1998 Elsevier Science B.V. All rights reser
ved.