ANIONIC-POLYMERIZATION OF STYRENE AT HIGH -TEMPERATURE IN ETHYLBENZENE WITH HIGH-CONCENTRATIONS OF MONOMERS

Citation
J. Couve et al., ANIONIC-POLYMERIZATION OF STYRENE AT HIGH -TEMPERATURE IN ETHYLBENZENE WITH HIGH-CONCENTRATIONS OF MONOMERS, European Polymer Journal, 34(3-4), 1998, pp. 347-349
Citations number
4
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00143057
Volume
34
Issue
3-4
Year of publication
1998
Pages
347 - 349
Database
ISI
SICI code
0014-3057(1998)34:3-4<347:AOSAH->2.0.ZU;2-Q
Abstract
The thermal decomposition of ethylbenzene solutions of n-butyllithium and polystyryllithium was observed between 50 and 100 degrees C by gas chromatography and UV spectroscopy, respectively. The initiator shows poor stability but the polymerisation can lead to controlled molecula r weights of living polymers by using a high concentration of monomer (about 50% by weight). (C) 1998 Elsevier Science Ltd. All rights reser ved.