Sja. Brown et al., PLUTONIC LITHICS IN IGNIMBRITES OF TAUPO VOLCANIC ZONE, NEW-ZEALAND -SOURCES AND CONDITIONS OF CRYSTALLIZATION, Chemical geology, 148(1-2), 1998, pp. 21-41
Plutonic rock fragments occur as rare accessory lithics within same of
the ignimbrites erupted from calderas and caldera complexes in centra
l Taupo Volcanic Zone (TVZ), New Zealand. The two main suites of pluto
nic lithics are: (1) medium to fine-grained granitoids and (2) fine-gr
ained dolerites and microdiorites. The granitoids are mostly medium-gr
ained rocks with both equigranular and granophyric intergrowth texture
s, the latter indicating rapid crystallisation at shallow crustal leve
ls. Biotite is the predominant mafic phase in most granitoid samples,
although rare hornblende and orthopyroxene-bearing granitoids also occ
ur. Glass occurs in some granitoid samples from Rotoiti ignimbrite, in
dicating that these samples were incompletely crystallised prior to er
uption. Dolerite and microdiorite fragments typically contain abundant
hornblende, and up to 10% vesicular interstitial glass. SiO2 abundanc
es in the granitoids range between 70.3 and 77.9%. They are weakly met
aluminous to weakly peraluminous and show an enrichment in Large Ion L
ithophile (Ln) elements (Rb, K, Ba), and a depletion in Nb, relative t
o MORE; similar to recent TVZ rhyolitic volcanic racks. Chemically and
petrographically the granitoids fall into two distinct groups: high-S
r granodiorites (120-205 ppm Sr), and chemically more evolved low-Sr m
onzogranites (26-65 ppm Sr), with an apparent compositional gap betwee
n the two. Eu/Eu anomalies and strong correlations between Al2O3, CaO
and Sr indicate that compositional variation between the two granitoi
d groups is dominantly controlled by plagioclase fractionation. The hi
gh- and low-Sr groups coincide with the highest and lowest Sr concentr
ations observed in TVZ rhyolites. REE data and Sr, Nd, Pb and O isotop
e ratios for granitoids are comparable to published data for TVZ rhyol
ites, and consequently they are considered to represent crystallised p
ortions of zoned silicic magma chambers associated with Quaternary TVZ
volcanic activity, and not fragments of older pre-TVZ basement. Most
granitoids are regarded as comagmatic with their host ignimbrites, but
those from Rotoiti ignimbrite have different mineral assemblages and
whole-rock chemistry to the host ignimbrite. These fragments appear to
be incompletely crystallised portions of an earlier magma system, pos
sibly the same system that generated the Matahina ignimbrite. Dolerite
s and microdiorites are geochemically similar to evolved high alumina
basalts erupted from the central TVZ and are considered to be intrusiv
e equivalents. (C) 1998 Elsevier Science B.V. All rights reserved.