ISOLATION AND CHARACTERIZATION OF A VANADIUM ETHYLIDYNE COMPLEX - THECRYSTAL-STRUCTURE OF [(CY2N)2V]2LI-MU(3)-O)(MU(2),ETA(1)-ETA(1)-CME) - AN UNUSUAL V2LIO CLUSTER

Authors
GAMBAROTTA S EDEMA JJH MINHAS RK
Citation
S. Gambarotta et al., ISOLATION AND CHARACTERIZATION OF A VANADIUM ETHYLIDYNE COMPLEX - THECRYSTAL-STRUCTURE OF [(CY2N)2V]2LI-MU(3)-O)(MU(2),ETA(1)-ETA(1)-CME) - AN UNUSUAL V2LIO CLUSTER, Journal of the Chemical Society, Chemical Communications, (19), 1993, pp. 1503-1504
Citations number
42
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
19
Year of publication
1993
Pages
1503 - 1504
Database
ISI
SICI code
0022-4936(1993):19<1503:IACOAV>2.0.ZU;2-W
Abstract
Reaction of VCl2(TMEDA)2 [TMEDA = N,N,N',N'-tetramethyienediamine] wit h Cy2NH [Cy = cyclohexyl] and Bu(n)Li in tetrahydrofuran led to the fo rmation of a complicated mixture of products from which a dinuclear et hylidyne complex [(Cy2N)2V]2(mu3,eta1-O)(mu2,eta1:eta1-CMe) 1 was isol ated.