Sg. Whittaker et al., PETROGENESIS OF 1.9 GA LIMESTONES AND DOLOSTONES AND THEIR RECORD OF PALEOPROTEROZOIC ENVIRONMENTS, Precambrian research, 90(3-4), 1998, pp. 187-202
Fibrous calcite cements from limestones of the Paleoproterozoic Pethei
Group in northwest Canada have relatively constant delta(13)C values,
near 1 parts per thousand, that indicate the C exogenic cycle of ca 1
.9 Ga ago had similar balances between oxidized and reduced reservoirs
of carbon as has existed throughout most of the Phanerozoic. Sr-87/Sr
-86 ratios of these cements are near 0.7051, and support a progressive
ly increasing influx of radiogenic Sr from continental weathering into
the Paleoproterozoic oceans. delta(18)O values of the cements vary fr
om -14 to -8.5 parts per thousand, although the original values of the
cements were probably higher because the cements have been subsequent
ly altered, as evidenced by their variable trace element contents. Pro
posed higher temperatures or substantially lower delta(18)O values of
ancient seawater based on such values may be in error. Fabric retentiv
e dolomites, generally regarded as syndepositional, also have variable
delta(18)O values, the highest of which are ca 30 greater than the hi
ghest values of the fibrous calcite cements. The dolomites have more r
adiogenic Sr isotopic compositions indicating that they formed from fl
uids that interacted with rocks such as those of the elastic sediments
which underlie the limestones. These fluids may have partially altere
d the delta(18)O values and chemical compositions of the fibrous calci
te cements. Late-stage calcitic and dolomitic cements that formed from
late diagenetic fluids have similar delta(18)O values and radiogenic
Sr isotopic ratios as the fabric retentive dolomites. If these potenti
ally syndepositional dolomites have had their primary isotopic composi
tions reset through interaction with diagenetic fluids, this would hav
e significant implications to other studies using early dolomite to co
nstrain ancient environmental conditions. (C) 1998 Elsevier Science B.
V.