A MICROPOROUS CARBON PRODUCED BY ARC-EVAPORATION

Citation
Sc. Tsang et al., A MICROPOROUS CARBON PRODUCED BY ARC-EVAPORATION, Journal of the Chemical Society, Chemical Communications, (19), 1993, pp. 1519-1522
Citations number
19
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
19
Year of publication
1993
Pages
1519 - 1522
Database
ISI
SICI code
0022-4936(1993):19<1519:AMCPBA>2.0.ZU;2-H
Abstract
A carbon soot formed by arc evaporation and activated by heating under carbon dioxide is found to have a surprisingly high internal micropor e volume (> 0.25 ml g-1) and an apparent BET surface area of ca. 700 m 2 g-1, a large proportion of the pores are ca. less-than-or-equal-to 5 angstrom; transmission electron microscopy shows a highly disordered microstructure, which electron irradiation readily transforms into qua si spherical concentric nanoparticles of diameter of ca. 60 angstrom, the carbon material, which is highly absorbent to methane, shows molec ular sieving properties and is more inert to oxidation than other form s of high surface area carbon.