Sc. Tsang et al., A MICROPOROUS CARBON PRODUCED BY ARC-EVAPORATION, Journal of the Chemical Society, Chemical Communications, (19), 1993, pp. 1519-1522
A carbon soot formed by arc evaporation and activated by heating under
carbon dioxide is found to have a surprisingly high internal micropor
e volume (> 0.25 ml g-1) and an apparent BET surface area of ca. 700 m
2 g-1, a large proportion of the pores are ca. less-than-or-equal-to 5
angstrom; transmission electron microscopy shows a highly disordered
microstructure, which electron irradiation readily transforms into qua
si spherical concentric nanoparticles of diameter of ca. 60 angstrom,
the carbon material, which is highly absorbent to methane, shows molec
ular sieving properties and is more inert to oxidation than other form
s of high surface area carbon.