The general concepts of x-ray and neutron reflectivity are outlined. T
heoretical principles are discussed at the beginning where both, the o
ptical treatment based on the solution of the Helmholtz equation and t
he kinematical scattering formalism are given. Afterwards experimental
standard setups are presented, and a small fraction of the work that
has been done in the past is discussed. The examples deal with scatter
ing from liquid thin films and polymer films where x-ray and neutron r
eflectivity are almost unique probes to obtain structural information.
This is in particular true for polymer/polymer interfaces where neutr
on reflectivity has one of its most prominent applications. Other exam
ples show how oxidation processes can be monitored by x-ray reflectivi
ty and how layer systems of technological importance, here CoSi2 layer
s, can be quantitatively characterized. Furthermore off-specular scatt
ering is briefly discussed and its importance for a complete analysis
emphazised.