T. Gehrke et al., IMPORTANCE OF EXTRACELLULAR POLYMERIC SUBSTANCES FROM THIOBACILLUS-FERROOXIDANS FOR BIOLEACHING, Applied and environmental microbiology, 64(7), 1998, pp. 2743-2747
Leaching bacteria such as Thiobacillus ferrooxidans attach to pyrite o
r sulfur by means of extracellular polymeric substances (EPS) (lipopol
ysaccharides). The primary attachment to pyrite at pH 2 is mediated by
exopolymer complexed iron(III) ions in an electrochemical interaction
with the negatively charged pyrite surface. EPS from sulfur cells pos
sess increased hydrophobic properties and do not attach to pyrite, ind
icating adaptability to the substrate or substratum.