A STEREOSELECTIVE ISOMERIZATION OF ALLYL SILYL ETHERS TO (E)-SILYL OR(Z)-SILYL ENOL ETHERS USING CATIONIC IRIDIUM COMPLEXES

Authors
OHMURA T SHIRAI Y YAMAMOTO Y MIYAURA N
Citation
T. Ohmura et al., A STEREOSELECTIVE ISOMERIZATION OF ALLYL SILYL ETHERS TO (E)-SILYL OR(Z)-SILYL ENOL ETHERS USING CATIONIC IRIDIUM COMPLEXES, Chemical communications, (13), 1998, pp. 1337-1338
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1998
Pages
1337 - 1338
Database
ISI
SICI code
1359-7345(1998):13<1337:ASIOAS>2.0.ZU;2-G
Abstract
A cationic iridium complex, prepared via the hydrogenation of [Ir(cod) (2)]PF6-2PPr(3) is found to be an excellent catalyst for the stereosel ective isomerization of primary allyl silyl ethers to (E)-enol ethers and secondary allyl ethers to (Z)-enol ethers.