STRUCTURE AND DYNAMICS OF ALL OF THE STEREOISOMERS OF EUROPIUM COMPLEXES OF TETRA(CARBOXYETHYL) DERIVATIVES OF DOTA - RING INVERSION IS DECOUPLED FROM COOPERATIVE ARM ROTATION IN THE RRRR AND RRRS ISOMERS

Authors
HOWARD JAK KENWRIGHT AM MOLONEY JM PARKER D PORT M NAVET M ROUSSEAU O WOODS M
Citation
Jak. Howard et al., STRUCTURE AND DYNAMICS OF ALL OF THE STEREOISOMERS OF EUROPIUM COMPLEXES OF TETRA(CARBOXYETHYL) DERIVATIVES OF DOTA - RING INVERSION IS DECOUPLED FROM COOPERATIVE ARM ROTATION IN THE RRRR AND RRRS ISOMERS, Chemical communications, (13), 1998, pp. 1381-1382
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1998
Pages
1381 - 1382
Database
ISI
SICI code
1359-7345(1998):13<1381:SADOAO>2.0.ZU;2-N
Abstract
The absolute configuration of the four stereoisomeric alpha-substitute d derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent o f pendant arm rotation and the (RRRR)-[EuL1a] complex which in the sol id state crystallises as a square antiprismatic structure.