[(DIPPNH)(2)AL(MU-NHDIPP)(2)LI.THF] AND [THF.LI(MU-NHCY)(3)SN(MU-NHCY)(3)LI.THF].C6H5ME, POTENTIAL BUILDING-BLOCKS FOR HETEROMETALLIC IMIDOCOMPOUNDS (DIPP=2,6-(PR2C6H3)-C-I)

Authors
BESWICK MA CHOI N HARMER CN MCPARTLIN M MOSQUERA MEG RAITHBY PR TOMBUL M WRIGHT DS
Citation
Ma. Beswick et al., [(DIPPNH)(2)AL(MU-NHDIPP)(2)LI.THF] AND [THF.LI(MU-NHCY)(3)SN(MU-NHCY)(3)LI.THF].C6H5ME, POTENTIAL BUILDING-BLOCKS FOR HETEROMETALLIC IMIDOCOMPOUNDS (DIPP=2,6-(PR2C6H3)-C-I), Chemical communications, (13), 1998, pp. 1383-1384
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1998
Pages
1383 - 1384
Database
ISI
SICI code
1359-7345(1998):13<1383:[A[>2.0.ZU;2-J
Abstract
[(DippNH)(2)Al(mu-NHDipp)(2)Li . thf] 1 and [thf . Li(mu-NHCy)(3)Sn(mu -NHCy)(3)Li . thf]. C6H5Me 2 are produced from the reactions of AlCl3 and SnCl4 or MeAlCl2 and MeSn(NMe2)(3) with the appropriate primary am ido lithium precursors [RNHLi; R = 2,6-(Pr2C6H3)-C-i (Dipp), C6H11 (CY )]; both complexes have ion-paired structures in the solid state with the retention of potentially reactive N-H functionality providing prec ursors for heterometallic species containing [M(NR)(x)(NHR)(n-x)]((1+x ))(-) anions (M = Al, n = 4; M = Sn, n = 6).