A statistical treatment of the number of secondary electrons, ions or
neutrals emitted as a consequence of projectile-solid collision is des
cribed. The multiplicity distribution of the ejected particles and the
ir correlation coefficients Q are defined and discussed. A random emis
sion model is analyzed analytically and some of its predictions are co
mpared with Monte Carlo simulations. This treatment provides basic gro
unds for coincidence counting analysis. It is shown that the secondary
ion emission of certain systems is strongly correlated, thus providin
g information about their desorption mechanism. Background material in
statistics and the Monte Carlo algorithm used are presented in Append
ices A-D. (C) 1998 Elsevier Science B.V. All rights reserved.