FUNCTIONAL ORGANOOXOTIN CARBOXYLATES

Authors
JAUMIER P JOUSSEAUME B
Citation
P. Jaumier et B. Jousseaume, FUNCTIONAL ORGANOOXOTIN CARBOXYLATES, Silicon, germanium, tin and lead compounds, 21(6), 1998, pp. 325-329
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
21
Issue
6
Year of publication
1998
Pages
325 - 329
Database
ISI
SICI code
0792-1241(1998)21:6<325:FOC>2.0.ZU;2-M
Abstract
Organooxotin carboxylates where the organic group linked to the tin is substituted by an ester group in various positions from the metal hav e been prepared by hydrolysis and reaction with acetic acid of the cor responding trialkynylorganotins. It was shown that, in solution, these compounds are hexameric with hexacoordinated tins. Strong coordinatin g effects of bridging carboxylato ligands prevent the ester groups to coordinate to the tin atoms.