SYNTHESIS AND CHARACTERIZATION OF OXOPHOSPHORYLCYCLOPENTADIENYL AND THIOPHOSPHORYLCYCLOPENTADIENYL TI(IV) THIOLATE COMPLEXES - CRYSTAL-STRUCTURES OF [(ETA(5)-C5H4P(S)PH-2)(ETA(5)-C5H4SIME3)TICL2] AND TA(5)-C5H4P(S)PH-2)(2)TI(SPH)(2)]CENTER-DOT-C4H10O

Authors
DELGADO E GARCIA MA HERNANDEZ E MANSILLA N MARTINEZCRUZ LA TORNERO J TORRES R
Citation
E. Delgado et al., SYNTHESIS AND CHARACTERIZATION OF OXOPHOSPHORYLCYCLOPENTADIENYL AND THIOPHOSPHORYLCYCLOPENTADIENYL TI(IV) THIOLATE COMPLEXES - CRYSTAL-STRUCTURES OF [(ETA(5)-C5H4P(S)PH-2)(ETA(5)-C5H4SIME3)TICL2] AND TA(5)-C5H4P(S)PH-2)(2)TI(SPH)(2)]CENTER-DOT-C4H10O, Journal of organometallic chemistry, 560(1-2), 1998, pp. 27-33
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
560
Issue
1-2
Year of publication
1998
Pages
27 - 33
Database
ISI
SICI code
0022-328X(1998)560:1-2<27:SACOOA>2.0.ZU;2-J
Abstract
New titanium (IV) complexes containing diphenyloxo- or diphenylthiopho sphorylcyclopentadienyl ligands are obtained by reaction of diphenylph osphinocyclopentadienyl derivatives with the appropriate oxidizer (S-8 or H2O2). The crystal structures of [(eta(5)-C5H4P(S)Ph-2)(eta(5)-C5H 4SiMe3)TiCl2] 3 and [(eta(5)-C5H4P(S)Ph-2)(2)Ti(SPh)(2)]. C4H10O 7 ind icate in both cases, a pseudo-tetrahedral arrangement around the titan ium atom. The two SPh ligands in compound 7 are orientated in opposite sites of the TiS2 plane, which suggests an anti conformation for this molecule. (C) 1998 Elsevier Science S.A. All rights reserved.