AN OCTAHEDRAL STANNYLMANGANESE STANNYLENE COMPLEX

Authors
WEIDENBRUCH M STILTER A SAAK W PETERS K VONSCHNERING HG
Citation
M. Weidenbruch et al., AN OCTAHEDRAL STANNYLMANGANESE STANNYLENE COMPLEX, Journal of organometallic chemistry, 560(1-2), 1998, pp. 125-129
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
560
Issue
1-2
Year of publication
1998
Pages
125 - 129
Database
ISI
SICI code
0022-328X(1998)560:1-2<125:AOSSC>2.0.ZU;2-4
Abstract
Treatment of decacarbonyldimanganese with the alkylarylstannylene RR'S n (2), R = 2,4,6-tBu(3)C(6)H(2), R' = CH2C(CH3)(2)-3,5-tBu(2)C(6)H(3), furnishes the tetracarbonyl-stannylmanganese stannylene complex 3, in which the tin atom of the stannyl group is part of a stannaindan ring system. Reaction of 2 with [(OC)(2)Fe(NO)(2)] yields the tetrahedral iron stannylene complex [OC(NO)(2)Fe = SnRR'] (4). The structures of 3 and 4 were determined by X-ray crystallography. (C) 1998 Elsevier Sci ence S.A. All rights reserved.