N. Toshima et T. Tominaga, ENHANCED CARRIER-TRANSFER IN MULTILAYERED ORGANIC THIN-FILM - APPLICATION TO ELECTROCHROMISM AND ELECTROLUMINESCENCE, Macromolecular symposia, 131, 1998, pp. 147-153
Multi-layered organic thin films were prepared by stepwise vapor depos
ition of planar molecules with delocalized pi-electrons on indium tin
oxide (ITO) glass or KCI crystalline surface. The order of the deposit
ion of pi-planar molecules with different redox potential can control
enhancement or inhibition of the hole or electron transfer according t
o the concept of ''sequential potential field'', or a potential cascad
e by the organization of redox components. This concept is here applie
d to electrochromic or electroluminescent devices composed of multi-la
yered organic thin films.