A theoretical model has been developed to simulate the operation of a
dual-piston pressure swing adsorption (PSA) system. In contrast to pre
vious models for this type of system, the pressure variation is calcul
ated directly from the specified movement of the pistons. The predicti
ons of the simulation are compared with experimentally observed pressu
re profiles under various operating conditions. The model provides a g
ood qualitative prediction of the system behaviour, although the exper
imental pressure profiles are generally somewhat attenuated relative t
o the predicted profiles. At slow speeds there is little phase differe
nce between the experimental profiles and the theoretical profiles cal
culated assuming local equilibrium, but for faster cycles (>10 rpm) ph
ase lags become increasingly evident, suggesting the progressive intru
sion of mass transfer resistance. (C) 1998 Elsevier Science B.V.