J. Parr et al., HYDROLYSIS, OXIDATION AND COMPLEXATION - THE REACTIONS OF TIN(II) CHLORIDE WITH A TRIPODAL SCHIFF-BASE LIGAND, INORGANIC CHEMISTRY COMMUNICATIONS, 1(5), 1998, pp. 159-160
The interaction of SnCl2. 2H(2)O and the heptadentate tripodal Schiff
base saltren yields in moderate yield the hexacoordinate Sn(IV) comple
x [Sn(saltren)] Cl (1). In addition, there is extensive destruction of
the ligand, yielding the component triamine and aldehydes. The crysta
l structure of [Sn(saltren)]Cl . (salicylaldehyde) (1 . (sal)), is rep
orted. (C) 1998 Elsevier Science S.A. All rights reserved.