MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - AN INTERESTING ANGULAR CHANGE IN RELATIVE SUBCLUSTER ORIENTATION IN THE OXIDATIVE PROTONATION OF [S2B17K18](-) TO [S2B17H17]

Authors
JELINEK T KENNEDY JD STIBR B THORNTONPETT M
Citation
T. Jelinek et al., MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - AN INTERESTING ANGULAR CHANGE IN RELATIVE SUBCLUSTER ORIENTATION IN THE OXIDATIVE PROTONATION OF [S2B17K18](-) TO [S2B17H17], INORGANIC CHEMISTRY COMMUNICATIONS, 1(5), 1998, pp. 179-181
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
5
Year of publication
1998
Pages
179 - 181
Database
ISI
SICI code
1387-7003(1998)1:5<179:MBCC-A>2.0.ZU;2-K
Abstract
Treatment of the macropolyhedral double-cluster anion [S2B17H18](-) wi th oxidising acids quantitatively generates neutral [S2B17H17], charac terised as its anion [S2B17H16](-). A significant change of similar to 34 degrees in the mutual orientation of the two sub-clusters is assoc iated with this two-electron oxidation. (C) 1998 Elsevier Science S.A. All rights reserved.