The performance of a tapered pressure swing adsorption (PSA) column is
investigated on the basis of rigorous nonisothermal numerical modelin
g, for simultaneous nitrogen purification and butane vapor recovery. T
he results indicate that the tapered column improves the process perfo
rmance when feeding from the wider end of the column and purging from
the narrower end. An optimum taper angle (5 degrees) is also found for
the constant length and volume system investigated with an order of m
agnitude increase in the light product purity. The favorable effects a
re manifested through complex temperature variations and corresponding
local concentration wave velocity variations associated with heating
and cooling effects that are caused by adsorption and desorption of th
e butane vapor. The favorable effects of a tapered PSA column also imp
rove as the heat effects become more pronounced.