SYNTHESIS AND PROPERTIES OF SILVER(I) AND COPPER(I) HELICATES WITH IMINE-BRIDGED OLIGOBIPYIDINE LIGANDS

Authors
STILLER R LEHN JM
Citation
R. Stiller et Jm. Lehn, SYNTHESIS AND PROPERTIES OF SILVER(I) AND COPPER(I) HELICATES WITH IMINE-BRIDGED OLIGOBIPYIDINE LIGANDS, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (7), 1998, pp. 977-982
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY → ACNP
ISSN journal
14341948
Issue
7
Year of publication
1998
Pages
977 - 982
Database
ISI
SICI code
1434-1948(1998):7<977:SAPOSA>2.0.ZU;2-K
Abstract
Oligobipyridine ligands containing one or two imine bridges were found to form double helicates by treatment with copper(I) or silver(I). Th e properties of the complexes are similar to those of oxapropylene-bri dged oligobipyridines. Titration of a mixture of the bis(bipyridine) a nd the tris(bipyridine) Ligands with silver(I) hexafluorophosphate sho wed that helicates formed with strict self-recognition.