PROTON ACCEPTOR PROPERTIES OF STERICALLY HINDERED PHOSPHINE-SUBSTITUTED DERIVATIVES IN H-BOND COMPLEXES

Authors
Citation
Ie. Boldeskul, PROTON ACCEPTOR PROPERTIES OF STERICALLY HINDERED PHOSPHINE-SUBSTITUTED DERIVATIVES IN H-BOND COMPLEXES, Journal of molecular structure, 448(2-3), 1998, pp. 171-176
Citations number
10
Categorie Soggetti
Chemistry Physical
ISSN journal
00222860
Volume
448
Issue
2-3
Year of publication
1998
Pages
171 - 176
Database
ISI
SICI code
0022-2860(1998)448:2-3<171:PAPOSH>2.0.ZU;2-X
Abstract
IR studies of H-bond complexes of sterically hindered phosphines were performed, as well as semi-empirical calculations of their protonated forms by the MNDO-H method. Correlations between the calculated and ex perimental values and interdependence of electron and steric factors a re discussed, (C) 1998 Elsevier Science B.V. All rights reserved.