CRYSTAL-STRUCTURE OF 1,1'-DIMETHYL-4,4'-B IPYRIDINIUM-OCTACHLORODIANTIMONATE(III)

Authors
JASCHINSKI B BLACHNIK R REUTER H
Citation
B. Jaschinski et al., CRYSTAL-STRUCTURE OF 1,1'-DIMETHYL-4,4'-B IPYRIDINIUM-OCTACHLORODIANTIMONATE(III), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(5-6), 1998, pp. 565-568
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
5-6
Year of publication
1998
Pages
565 - 568
Database
ISI
SICI code
0932-0776(1998)53:5-6<565:CO1I>2.0.ZU;2-0
Abstract
The title compound was prepared by reaction of SbCl3 with 1,1'-dimethy l-4,4'-bipyridinium-chloride in methanol. The single crystal structure gave the following data: [C12H14N2][Sb2Cl8] (1) space group P1, Nr. 1 , with a = 570.68(7) pm, b = 938.57(14) pm, c = 1174.27(11) pm, alpha = 66.72(9)degrees, beta = 89.304(12)degrees, gamma = 78.684(11)degrees , and Z = 1. The compound has a small SHG effect and a phase transitio n at 272 degrees C with an enthalpy of transition of 6.54 kJ mol(-1).