POLYSULFONYLAMINES, CIII [1] A HYDROXYLAM INE WITH A REMARKABLY SHORTO-N BOND - CRYSTAL AND MOLECULAR-STRUCTURE OF MEO-N(SO2ME)(2)

Authors
NAVEKE M BLASCHETTE A JONES PG
Citation
M. Naveke et al., POLYSULFONYLAMINES, CIII [1] A HYDROXYLAM INE WITH A REMARKABLY SHORTO-N BOND - CRYSTAL AND MOLECULAR-STRUCTURE OF MEO-N(SO2ME)(2), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(5-6), 1998, pp. 634-636
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
5-6
Year of publication
1998
Pages
634 - 636
Database
ISI
SICI code
0932-0776(1998)53:5-6<634:PC[AHI>2.0.ZU;2-N
Abstract
The crystal structure of the known title compound was determined by lo w-temperature X-ray diffraction (orthorhombic, space group Pbcn, Z = 4 ). The molecule displays an unusually short ON bond, a relatively long C-O bond and a moderately pyramidal O-NS2 skeleton (O-N 133.1, C-O 14 8.5 pm, sum of bond angles at N: 347.4 degrees).