LOW-ENERGY-ELECTRON SCATTERING BY CF3CL, CF2CL2, CFCL3 AND CCL4

Citation
J. Randell et al., LOW-ENERGY-ELECTRON SCATTERING BY CF3CL, CF2CL2, CFCL3 AND CCL4, Journal of physics. B, Atomic molecular and optical physics, 26(19), 1993, pp. 3423-3434
Citations number
42
Categorie Soggetti
Physics, Atomic, Molecular & Chemical",Optics
ISSN journal
09534075
Volume
26
Issue
19
Year of publication
1993
Pages
3423 - 3434
Database
ISI
SICI code
0953-4075(1993)26:19<3423:LSBCCC>2.0.ZU;2-9
Abstract
We report the results of electron transmission experiments in the chlo rofluoromethanes and CCl4 in the energy range from less than 10 meV to a few hundred meV, using a magnetically confined electron beam, gener ated from a high resolution, synchrotron photoionization source on Sup erACO, LURE. Scattering spectra show evidence of electron attachment, Ramsauer-Townsend effects, and pure rotational and rovibrational inela stic scattering. For CF3Cl and CF2Cl2 we analyse the inelastic scatter ing phenomena in terms of the first Born approximation, showing that t his gives a good fit to the form of the variation of the pure rotation ally inelastic cross section with electron kinetic energy.