We studied the unlubricated sliding wear behaviour of Ni-P-W compositi
onally modulated coatings on mild steel pins, sliding against hardened
steel discs in a pin-on-disc set-up. The multilayered coatings consis
ted of high and low W-content layers. The linear velocity was constant
for all tests, and the normal loads used were 200, 500, 800 and 1100
g. Coatings of various layer periodicities were studied. Friction coef
ficients were recorded during the tests, and it was found that after a
running-in period of about 30 m, friction coefficients reached a stea
dy slate. An increase in the normal load caused a decrease in friction
coefficients regardless of the layer periodicity of the coating. Coat
ings with a smaller layer periodicity showed a better wear resistance
than those with larger layer periodicities. Two major wear mechanisms
were identified: brittle fracture of the individual layers accompanied
by crack deflection at the interfaces between the layers and delamina
tion of parts of the coating. The first mechanism was active for the w
hole range of loads, whereas the second was operative only for loads o
f 800 and 1100 g. (C) 1998 Elsevier Science S,A.