PARAMETERS OF SYNTHESIS OF HYDRAZIDES AND 1,2-DIACYLHYDRAZINES BY THERMAL-DECOMPOSITION OF HYDRAZINE SALTS OF ALIPHATIC CARBOXYLIC-ACIDS

Citation
Ag. Drozdetskii et al., PARAMETERS OF SYNTHESIS OF HYDRAZIDES AND 1,2-DIACYLHYDRAZINES BY THERMAL-DECOMPOSITION OF HYDRAZINE SALTS OF ALIPHATIC CARBOXYLIC-ACIDS, Russian journal of applied chemistry, 71(2), 1998, pp. 302-306
Citations number
16
Categorie Soggetti
Chemistry Applied
ISSN journal
10704272
Volume
71
Issue
2
Year of publication
1998
Pages
302 - 306
Database
ISI
SICI code
1070-4272(1998)71:2<302:POSOHA>2.0.ZU;2-J
Abstract
zThe reaction parameters were refined for synthesis of hydrazides and 1,2-diacylhydrazines by thermal decomposition of salts of aliphatic ca rboxylic acids of the general formulas RCOOH . N2H4. H2O and 2RCOOH . N2H4. H2O (R = C2H5-C8H17). Derivatograms for series of compounds were obtained. The effect of hydrazine hydrate excess, temperature, reacti on duration, and crystallization conditions on the yield and quality o f hydrazides of C-7-C-9 carboxylic acids was studied.