B. Lukyanchuk et al., THE ROLE OF EXCITED SPECIES IN UV-LASER MATERIALS ABLATION .1. PHOTOPHYSICAL ABLATION OF ORGANIC POLYMERS, Applied physics. A, Solids and surfaces, 57(4), 1993, pp. 367-374
UV-laser ablation is described in terms of a two-level system in which
the excitation energy is dissipated via stimulated emission, thermal
relaxation, and activated desorption of excited species. For thermal r
elaxation times t(T) > 10)(-9) s and DELTAE << DELTAE (activation ene
rgies for excited-state and ground-state species) the model predicts h
igh ablation rates at moderate surface temperatures, typically below 2
000-degrees-C.