High-accuracy thermal conductivity measurements were carried out on tw
o samples of pure aluminium below 4.2 K. Along with electrical resisti
vity measurements on one of the samples and high-accuracy electrical r
esistivity measurements available in the literature, these results per
mitted a determination of the electron-electron scattering terms in th
e thermal and electrical resistivities. The coefficients of these term
s are in very good agreement with the values predicted by MacDonald. I
n addition, the electron-phonon component rho(ep) of the electrical re
sistivity was successfully separated from the component rho(d) due to
deviations from Matthiessen's rule.