The method was developed allowing quantitative extraction of fulvic ac
ids from soil samples in the form close to native. Formation of gel-li
ke and soluble forms of iron(III) fulvates in the systems containing e
quivalent amounts of iron(III) and fulvic acid was studied within pH r
ange 1-9. The molecular structure of fulvates and the mechanism of tra
nsformation of gel to soluble forms was analyzed by IR spectroscopy. D
istribution of microamounts of europium between gel-like iron fulvates
and their solutions was studied. The correlation between phase distri
bution of europium and solubilization of iron(III) fulvates was analyz
ed.