L. Bronsard et al., A MULTIPHASE MULLINS-SEKERKA SYSTEM - MATCHED ASYMPTOTIC EXPANSIONS AND AN IMPLICIT TIME DISCRETIZATION FOR THE GEOMETRIC EVOLUTION PROBLEM, Proceedings of the Royal Society of Edinburgh. Section A. Mathematics, 128, 1998, pp. 481-506
We propose a generalisation of the Mullins-Sekerka problem to model ph
ase separation in multi-component systems. The model includes equilibr
ium equations in bulk, the Gibbs-Thomson relation on the interfaces, Y
oung's law at triple junctions, together with a dynamic law of Stefan
type. Using formal asymptotic expansions, we establish the relationshi
p to a transition layer model known as the Cahn-Hilliard system. We in
troduce a notion of weak solutions for this sharp interface model base
d on integration by parts on manifolds, together with measure theoreti
cal tools. Through an implicit time discretisation, we construct appro
ximate solutions by stepwise minimisation. Under the assumption that t
here is no loss of area as the time step tends to zero, we show the ex
istence of a weak solution.