HETEROGENEOUS ASYMMETRIC EPOXIDATION OF CIS-ALLYLIC ALCOHOLS - USE OFPOLYMER-SUPPORTED TI(IV)-CATALYST

Authors
KARJALAINEN JK HORMI OEO SHERRINGTON DC
Citation
Jk. Karjalainen et al., HETEROGENEOUS ASYMMETRIC EPOXIDATION OF CIS-ALLYLIC ALCOHOLS - USE OFPOLYMER-SUPPORTED TI(IV)-CATALYST, Tetrahedron : asymmetry, 9(12), 1998, pp. 2019-2022
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
12
Year of publication
1998
Pages
2019 - 2022
Database
ISI
SICI code
0957-4166(1998)9:12<2019:HAEOCA>2.0.ZU;2-6
Abstract
Heterogeneous asymmetric epoxidation of cis-allylic alcohols with tita nium isopropoxide and tert-butyl hydroperoxide has been achieved using a branched/crosslinked poly(tartrate ester) ligand. The enantioselect ivities and chemical yields obtained are at least comparable to low mo lecular weight tartrate ligands, (C) 1998 Published by Elsevier Scienc e Ltd. All rights reserved.