Orthogonal polynomials were used to model transformations between stan
dards and plate coordinates as well as relations between two plate coo
rdinates. Thanks to orthogonal functions, the estimates of model coeff
icients are uncorrelated and so are coefficient accuracies. We determi
ne the standard deviation function of a given transform. This function
gives a quantitative assessment of the accuracy and the significance
of the relations between two coordinate systems. In the present articl
e we shall give a general determination of the ultimate performances a
ccessible with a given set of data. We analyse the accuracy of 4th ord
er transform in astrometric reduction of Schmidt plates. Using PPM sta
rs, the 4th order transform accuracy is 1 mum or 0.065 arcsec. We foun
d that the 4th order polynomials did not model any significant distort
ions and that a 3rd order transform was sufficient at this level of ac
curacy. Finally, by comparing two similar Schmidt plates, we searched
for plate distortions with different scale lengths. We found significa
nt small amplitude distortions (above 1 mum) that could only be modell
ed by using a very high order transform. These distortions, reflecting
image quality or performance of the measuring machine, illustrate the
current limiting accuracy of Schmidt plate astrometry.