Yi. Tarasevich et al., CHROMATOGRAPHIC AND MOLECULAR STATISTICAL STUDIES OF STRUCTURAL AND ENERGY CHARACTERISTICS OF SURFACE MICROPORES OF SILICATES AND SILICA ADSORBENTS, Pure and applied chemistry, 65(10), 1993, pp. 2257-2264
A comprehensive approach to the investigation of structural and adsorp
tion-selective characteristics of surface-porous silicates and silica
adsorbents is developed, combining the chromatographic measurements an
d molecular statistical calculations involving the model pore structur
e and the detailed molecule-surface interaction potential. The method
is capable to describe the non-specific and weak specific adsorption o
n microporous surface and can be applied to the wide class of micropor
ous adsorbents.