THE ASYMMETRIC SOLVOMERCURATION-DEMERCURATION OF OLEFINS IN CHIRAL MICELLAR SYSTEMS

Authors
ZHANG YM BAO WL DONG H
Citation
Ym. Zhang et al., THE ASYMMETRIC SOLVOMERCURATION-DEMERCURATION OF OLEFINS IN CHIRAL MICELLAR SYSTEMS, Synthetic communications, 23(21), 1993, pp. 3029-3035
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
23
Issue
21
Year of publication
1993
Pages
3029 - 3035
Database
ISI
SICI code
0039-7911(1993)23:21<3029:TASOOI>2.0.ZU;2-B
Abstract
The solvomercuration-demercuration of olefins in chiral micelles were investigated. The chiral carbinols can be obtained by asymmetric oxyme rcuration of prochiral olefins with NaBH4. A satisfactory result was a chieved. The highest e.e.% was up to 96%.