Macrosegregation was investigated in longitudinal sections of continuo
usly cast, experimental slabs of austenitic stainless steel and carbon
-manganese steel. The macro-mapping technique was applied to investiga
te austenitic stainless steel slab sections. The method was based on e
lectron probe microanalysis that was applied in a step-point mode to l
ocally investigate segregation areas. The same stainless steel specime
ns and carbon-manganese steel specimens were etched to reveal the segr
egation structure. The macrosegregation in three carbon-manganese stee
l slabs was represented by etch-prints. The quantitative investigation
of structure was performed directly on the macroetched specimens and
on the etch-prints. The morphology of macrostructure was characterised
by new parameters: segregation factor M, width of a segregation band
W-0.5, centreline segregation intensity C and the heterogeneity index
H. The segregation factor M was proportional to the inhomogeneity in s
egregate size distribution and to the segregate area fraction. W0.5 wa
s defined as the area where the segregate area fraction is greater or
equal to half of the maximum value of measured area fractions. Paramet
er C equal to a ratio M-max/W-0.5, represented the intensity of centre
line segregation. The heterogeneity index H was based on the measureme
nts of mean size of segregates and the mean free path within segregate
areas. For a homogeneous structure the heterogeneity index is zero an
d it increases with growing inhomogeneity of a macrostructure.