STRUCTURES OF (ETA(1)-FLUORENYL)RE(CO)(5) AND (ETA(5)-FLUORENYL)RE(CO)(3) AND THEIR THERMAL INTERCONVERSION IN SOLID MATRICES

Authors
MEJDRICH AL HANKS TW
Citation
Al. Mejdrich et Tw. Hanks, STRUCTURES OF (ETA(1)-FLUORENYL)RE(CO)(5) AND (ETA(5)-FLUORENYL)RE(CO)(3) AND THEIR THERMAL INTERCONVERSION IN SOLID MATRICES, Synthesis and reactivity in inorganic and metal-organic chemistry, 28(6), 1998, pp. 953-973
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
28
Issue
6
Year of publication
1998
Pages
953 - 973
Database
ISI
SICI code
0094-5714(1998)28:6<953:SO(A(>2.0.ZU;2-6
Abstract
The crystal structures of (eta(1)-fluorenyl)Re(CO)(5) (1) and (eta(5)- fluorenyl)Re(CO)(3) (2) are described and the thermal conversion of (1 ) to (2) in polymer matrices is demonstrated. The reverse reaction cou ld not be effected in solid matrices.