T. Zaharescu et al., RADIOCHEMICAL PROCESSING OF EPDM NR BLENDS, Journal of macromolecular science. Pure and applied chemistry, A35(7-8), 1998, pp. 1093-1102
Radiochemical crosslinking of polymer systems consisting of ethylene-p
ropylene terpolymer (EPDM) and natural rubber (NR) is studied. Three b
inary blends (3:1, 1:1 and 1:3 w/w) were exposed to gamma-rays (Cs-137
) at various doses (up to 300 kGy). The gel content of irradiated mixt
ures were determined. Oxidation stability was evaluated by isothermal
oxygen uptake in air at normal pressure. The contribution of each comp
onent to the oxidation stability of stud-led blends is discussed. The
application of first derivative of [O-2]= f(t) to the estimation of st
ability under oxidation is presented.