SYNTHESIS AND CYCLIZATION OF PHOSPHORYLATED BETA-ALLENIC AMINES

Authors
AMEDJKOUH M FAURE R HATEM J TORDO P GRIMALDI J
Citation
M. Amedjkouh et al., SYNTHESIS AND CYCLIZATION OF PHOSPHORYLATED BETA-ALLENIC AMINES, Phosphorus, sulfur and silicon and the related elements, 126, 1997, pp. 53-64
Citations number
32
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
126
Year of publication
1997
Pages
53 - 64
Database
ISI
SICI code
1042-6507(1997)126:<53:SACOPB>2.0.ZU;2-K
Abstract
Phosphorylated beta-allenic amines were obtained by aminophosphorylati on of beta-allenic aldehydes and ketones. When treated by silver tetra fluoroborate in methylene chloride, they generated phosphorylated nitr ogen cycles such as 1-pyrrolines and 1.2,3,6-tetrahydropyridines, with dephosphorylation of the latter tetrahydropyridines producing 3,6-dih ydropyridines.