NEW DERIVATIVES OF IMINOCYCLODIPHOSPHAZANE, CHLOROPHOSPHAZOBENZYLIDENECYANOETHYL KETONE AND DICINNAMOYLPHOSPHORTRIAMIDE

Citation
Ha. Emam et al., NEW DERIVATIVES OF IMINOCYCLODIPHOSPHAZANE, CHLOROPHOSPHAZOBENZYLIDENECYANOETHYL KETONE AND DICINNAMOYLPHOSPHORTRIAMIDE, Phosphorus, sulfur and silicon and the related elements, 126, 1997, pp. 283-289
Citations number
8
ISSN journal
10426507
Volume
126
Year of publication
1997
Pages
283 - 289
Database
ISI
SICI code
1042-6507(1997)126:<283:NDOIC>2.0.ZU;2-5
Abstract
[(Arylidenecyanoacetyl)imino]cyclodiphosphazanes 3,4-chloroanilinodich lorophosphazo (4-nitrobenzylidene) cyanomethyl ketone 5 [(4-substitute d benzylidenecyanoacetamido) (4-substituted anilino)] chlorophosphazob enzylidenecyanomethyl ketone 6 and di[(p-nitro-alpha-cyanocinnamoyl) ( p-tolyl)]phosphortiamide 7 were synthesized from the reaction between cyclodiphosphazanes 1 and arylidene-cyano-acetamides 2. The postulated mechanism for the formation of such products were rationalized. The s tructures assigned were supported by UV, IR, H-1 NMR and mass spectra.