SILICONE GREASE AS A PRECURSOR TO A PSEUDOCROWN ETHER LIGAND - CRYSTAL-STRUCTURE OF [K-]4(]3[K(ME2SIO)7+][INH(CH2CME3)3)

Authors
CHURCHILL MR LAKE CH CHAO SHL BEACHLEY OT
Citation
Mr. Churchill et al., SILICONE GREASE AS A PRECURSOR TO A PSEUDOCROWN ETHER LIGAND - CRYSTAL-STRUCTURE OF [K-]4(]3[K(ME2SIO)7+][INH(CH2CME3)3), Journal of the Chemical Society, Chemical Communications, (20), 1993, pp. 1577-1578
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
20
Year of publication
1993
Pages
1577 - 1578
Database
ISI
SICI code
0022-4936(1993):20<1577:SGAAPT>2.0.ZU;2-3
Abstract
The crystallization of K[InH(CH2CMe3)3] from heptane in the presence o f silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-(Me2SiO)7 ligand ; K+...O distances range from 2.86(3) to 2.99(4) angstrom.