REDUCTION OF THE TRANSITION-TEMPERATURES IN MESOMORPHIC LANTHANIDE COMPLEXES BY THE EXCHANGE OF COUNTERIONS

Authors
BINNEMANS K GALYAMETDINOV YG COLLINSON SR BRUCE DW
Citation
K. Binnemans et al., REDUCTION OF THE TRANSITION-TEMPERATURES IN MESOMORPHIC LANTHANIDE COMPLEXES BY THE EXCHANGE OF COUNTERIONS, Journal of materials chemistry (Print), 8(7), 1998, pp. 1551-1553
Citations number
26
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry (Print) → ACNP
ISSN journal
09599428
Volume
8
Issue
7
Year of publication
1998
Pages
1551 - 1553
Database
ISI
SICI code
0959-9428(1998)8:7<1551:ROTTIM>2.0.ZU;2-9
Abstract
Metathesis of the chloride anion in the mesomorphic lanthanide complex es [LnL(LH)(2)][Cl](2) (LH = salicylaldimine; Ln = lanthanide element) by dodecyl sulfate (DOS) leads to the complexes [LnL(LH)(2)][DOS](2), which have wider mesomorphic ranges and lower clearing points.