LASER PHOTOLYSIS OF LIQUID BENZENE AND HEXAFLUOROBENZENE - GRAPHITIC AND POLYMERIC CARBON FORMATION AT AMBIENT-TEMPERATURE

Authors
URBANOVA M BASTL Z PLZAK Z SUBRT J GREGORA I VORLICEK V POLA J
Citation
M. Urbanova et al., LASER PHOTOLYSIS OF LIQUID BENZENE AND HEXAFLUOROBENZENE - GRAPHITIC AND POLYMERIC CARBON FORMATION AT AMBIENT-TEMPERATURE, Carbon (New York), 36(5-6), 1998, pp. 517-520
Citations number
19
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Carbon (New York) → ACNP
ISSN journal
00086223
Volume
36
Issue
5-6
Year of publication
1998
Pages
517 - 520
Database
ISI
SICI code
0008-6223(1998)36:5-6<517:LPOLBA>2.0.ZU;2-M
Abstract
ArF laser-induced liquid-phase photolysis of benzene and hexafluoroben zene afford similar products which are polyaromatic hydrocarbons or fl uorocarbons with the preponderance of biphenyl or decafluorobiphenyl, graphite, and polymeric H-containing or F-containing carbon. The remar kable feature is that the graphite formation occurs at ambient tempera ture of the irradiated liquids; photolytic graphitization modes must t herefore be different from those occurring in thermally-induced graphi tization at temperatures above 2500 degrees C. (C) 1998 Elsevier Scien ce Ltd. All rights reserved.