M. Strehle et al., FEMTOSECOND TIME-RESOLVED RYDBERG WAVE-PACKET DYNAMICS IN THE 2-ELECTRON SYSTEM CALCIUM, Physical review. A, 58(1), 1998, pp. 450-455
We have investigated the radial Rydberg wave-packet dynamics in the tw
o-valence-electron atom calcium by femtosecond pump-probe spectroscopy
. The classical periodic motion of the Kepler electron as well as the
quantum mechanical revival structure were observed when employing the
phase sensitive detection technique. Preliminary results are reported
on Rydberg wave-packet autoionization under the influence of an isolat
ed excitation of the remaining outer core electron.