From the aerial parts of Machaeranthera tanacetifolia the known 12-hyd
roxy-ent-kauren-16-en-19-oic acid and the two previously unknown (-)-1
1-O-alpha-D-arabinopyranosyl-beta-eudesmol and (+)-11-O-beta-L-arabino
pyranosyl-beta-eudesmol were isolated. The structure elucidation of th
ese compounds was based on spectroscopic and chemical evidences. (+)-1
1-O-beta-L-Arabinopyranosyl-beta-eudesmol was fully characterized by X
-ray analysis of its peracetate derivative. According with these resul
ts, we propose that the previously reported (+)-11-O-alpha-arabinopyra
nosyl-beta-eudesmol and 11-O-alpha-D-arabinopyranosyl-beta-eudesmol ar
e identical to (+)-11-O-beta-L-arabinopyranosyl-beta-eudesmol. (C) 199
8 Elsevier Science Ltd. All rights reserved.