Dipole resonant x-ray scattering from ordered Mn 3d orbitals in LaMnO3
has been observed near the Mn K-absorption edge. The polarization of
the scattered photons is rotated from sigma to pi' and the azimuthal a
ngle dependence shows a characteristic twofold symmetry. A theory for
the resonant scattering mechanism has been developed by considering th
e splitting of the Mn 4p levels due to the Mn 3d orbital ordering. The
order parameter of the orbital ordering decreases above the Neel temp
erature (T-N = 140 K) and disappears at T-0 = 780 K, concomitant with
a structural phase transition.