K. Kidena et al., INVESTIGATION ON COAL PLASTICITY - CORRELATION OF THE PLASTICITY AND A TGA-DERIVED PARAMETER, Energy & fuels, 12(4), 1998, pp. 782-787
In order to investigate coal plasticity, thermogravimetric analyses (T
GA) of 18 kinds of coking coal were carried out. When coals are heated
under an inert atmosphere, weight loss appears at around 400-500 degr
ees C. We found that the maximum rates of weight loss normalized by th
e amount of total weight loss up to 1000 degrees C showed a good corre
lation with Gieseler maximum fluidity of the sample coals. This result
means that effective generation of tar governs the degree of fluidity
of coal, supporting strongly the contribution of low-molecular compon
ents, metaplast, to the plastic behavior and fluidity of coking coals
during the carbonization process. In addition to this, the analyses of
tar or gaseous products evolved during heat treatment were also condu
cted in order to compare structural differences of these fractions amo
ng a series of coking coals. The effect of heating rate on TGA of the
sample coals was also investigated.