J. Gspann, CLUSTER DEPOSITION AND CLUSTER EROSION WITH HIGH-INTENSITY IONIZED CLUSTER BEAMS, Zeitschrift fur Physik. D, Atoms, molecules and clusters, 26, 1993, pp. 174-176
Cluster beams of high intensity as resulting from condensation in adia
batic nozzle expansions of pure gases or vapors can be used either for
thin film deposition or for substrate erosion, depending on the clust
er impact energy. For deposition, high-intensity cluster beams of zinc
and of silver have been obtained for the first time from pure metal v
apor nozzle expansions. The clusters contain several thousand atoms of
zinc, or several hundred atoms of silver, respectively. Reflecting th
in films have been deposited without ionizing and accelerating the clu
ster beams. For purposes of erosion, ionized clusters have to be accel
erated to impact speeds larger than about 10 km/s in order to get surf
ace erosion via shock wave induced crater formation. Crater dimensions
of some nanometers are estimated, providing a limit for the spatial r
esolution of cluster impact lithography (CIL).