SYNTHESIS AND CRYSTAL-STRUCTURES OF LITHIUM AND POTASSIUM TRIAZENIDE COMPLEXES

Authors
GANTZEL P WALSH PJ
Citation
P. Gantzel et Pj. Walsh, SYNTHESIS AND CRYSTAL-STRUCTURES OF LITHIUM AND POTASSIUM TRIAZENIDE COMPLEXES, Inorganic chemistry, 37(14), 1998, pp. 3450
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
14
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:14<3450:SACOLA>2.0.ZU;2-A
Abstract
Reaction of the 1,2,3-triazene Tol-N=N-NH-ToL with bases Li(N(SiMe3)(2 ), n-BuLi, KH, K(N(SiMe3)(2), and KO-t-Bu results in deprotonation of the triazene to give the lithium and potassium triazenide complexes. B oth have been characterized structurally and have a dimeric core. Howe ver, the bonding of the triazenide to the metals is very different.