REACTION OF ORGANOLITHIUM REAGENTS WITH [2-(PHENYL-KAPPA-C-2'),PYRIDINE-KAPPA-N]RHENIUM(I) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF ACYL RHENATE SPECIES

Authors
DJUKIC JP DOTZ KH PFEFFER M DECIAN A FISCHER J
Citation
Jp. Djukic et al., REACTION OF ORGANOLITHIUM REAGENTS WITH [2-(PHENYL-KAPPA-C-2'),PYRIDINE-KAPPA-N]RHENIUM(I) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF ACYL RHENATE SPECIES, Inorganic chemistry, 37(14), 1998, pp. 3649
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
14
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:14<3649:ROORW[>2.0.ZU;2-X
Abstract
Addition of phenyllithium and methyllithium to tetracarbonyl[2-(phenyl -kappa C-2'), pyridine-kappa N]rhenium(I), 1, affords novel anionic ac yl species that result from selective nucleophilic addition at the axi al carbonyl ligand of the chelated Re(CO)(4) species.